You haven't mentioned whether you actually have a problem with the boiler, if it's just that you can't see a pilot light then there's no problem because the Potterton Performa 24 does NOT have a permanent pilot light. It is a fanned flued combination boiler, when there is demand for heat (either central heating or hot water) the fan runs, a pressure switch sends a signal back to the PCB which in turn starts the ignition and opens the gas valve, the spark igniter is also a flame sensor and sends a signal back to the PCB to tell it the burner is on, if it doesn't sense a flame the sequence starts all over again.
If you have hot water but no central heating, make sure the programmer (timeclock) is switched to the demand mode (i.e. your central heating is switched on) and that your room stat (if fitted) is turned up and that the dial on the front of the boiler points to the symbol that shows a tap and a radiator.
If you have central heating but no hot water, the diverter valve is faulty.
If you have neither, make sure the isolation switch is switched on and that the 'power on' LED is lit, and that the dial on the front of the boiler points to either the tap or the tap and radiator. If you still get nothing, go outside to where the flue is and listen for the sound of the fan blowing, if you can't hear it there is a problem with either the fan (£150), the PCB (£100), the pressure switch (£25ish) or the tube to the pressure switch (£10), if this is the case please please please only let a CORGI registered gas engineer find the fault and repair it. Hope this helps.